| Preface | 5 |
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| Contents | 7 |
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| Chapter 1 Introduction | 10 |
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| 1.1 Global Energy Sources | 10 |
| 1.2 Fossil Fuel Sources | 12 |
| 1.2.1 The History of Petroleum | 13 |
| 1.2.2 Petroleum Refining | 15 |
| 1.2.3 Petroleum Products and Fuels | 18 |
| 1.2.4 Coal | 22 |
| 1.2.5 Chemicals and Fuels from Coal | 24 |
| 1.2.6 Natural Gas | 26 |
| 1.2.7 Gas Hydrates | 26 |
| 1.2.8 Oil Shale | 27 |
| 1.2.9 Tar Sands | 28 |
| 1.2.10 Natural Bitumen and Extra-heavy Oil | 29 |
| 1.3 Renewable Energy Sources | 30 |
| 1.3.1 Biomass | 31 |
| 1.3.1.1 Marine Biomass | 37 |
| 1.3.1.2 Biofuels from Biomass | 38 |
| 1.3.1.3 Bio-oil | 43 |
| 1.3.1.4 Biogas | 45 |
| 1.3.1.5 Fischer-Tropsch Liquids | 46 |
| 1.3.1.6 Biohydrogen | 47 |
| 1.3.1.7 Sugar from Biomass | 49 |
| 1.3.2 Hydropower | 52 |
| 1.3.3 Geothermal Energy | 55 |
| 1.3.4 Wind Energy | 56 |
| 1.3.5 Solar Energy | 57 |
| 1.3.6 Other Renewable Energy Sources | 59 |
| 1.3.7 Municipal Solid Waste and Landfill Gas | 59 |
| 1.4 Nuclear Fuel Sources | 61 |
| 1.5 Summary | 62 |
| Chapter 2 Natural Gas | 66 |
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| 2.1 Introduction | 66 |
| 2.2 Definition and History | 68 |
| 2.3 Origin of Natural Gas | 69 |
| 2.4 Natural Gas Resources | 70 |
| 2.5 Natural Gas Production, Consumption, and Distribution | 71 |
| 2.6 Compressed Natural Gas | 74 |
| 2.7 Liquefied Natural Gas | 75 |
| 2.8 Contribution of Natural Gas to Global Warning | 76 |
| 2.9 Use of Natural Gas | 77 |
| 2.9.1 Industrial Uses | 78 |
| 2.9.2 Residential Use | 79 |
| 2.9.3 Electricity Generation using Natural Gas | 80 |
| 2.9.4 Commercial Use | 81 |
| 2.9.5 Natural Gas in the Transportation Sector | 81 |
| 2.10 Importance of Natural Gas | 82 |
| 2.11 Environmental Impacts | 82 |
| 2.12 Summary | 84 |
| Chapter 3 Gas Hydrates | 86 |
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| 3.1 Introduction | 86 |
| 3.1.1 Definition | 88 |
| 3.1.2 History | 89 |
| 3.1.3 Gas Hydrate Origin and Formation | 90 |
| 3.1.4 Clathrates and Crystalline Clathrate Solids | 94 |
| 3.1.5 Storage of Hydrogen in Clathrates | 95 |
| 3.2 Chemical Structures | 96 |
| 3.2.1 Chemical Structure of the Water Molecule | 96 |
| 3.2.2 Chemical Structure of the Methane Molecule | 98 |
| 3.2.3 Crystalline Structure of Water Ice | 99 |
| 3.2.4 Crystalline Structure of Gas Hydrate | 100 |
| 3.3 Crystal Types of Gas Hydrates | 101 |
| 3.3.1 Clathrate Structure I | 103 |
| 3.3.2 Clathrate Structure II | 104 |
| 3.3.3 Clathrate Structure H | 105 |
| 3.4 Methane Gas Fuel | 107 |
| 3.4.1 Combustion of Methane | 109 |
| 3.4.2 Main Reactions of Methane | 112 |
| 3.5 Summary | 116 |
| Chapter 4 Methane Gas Hydrate: as a Natural Gas Source | 122 |
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| 4.1 Introduction | 122 |
| 4.2 Importance of Methane Hydrates | 123 |
| 4.3 Global Climate Change | 125 |
| 4.3.1 Air Pollution | 125 |
| 4.3.2 Greenhouse Effect | 130 |
| 4.3.3 Global Warming | 131 |
| 4.3.4 Arguments Against Global Warming | 134 |
| 4.3.5 Kyoto Protocol | 134 |
| 4.3.6 Carbon Credits | 135 |
| 4.3.7 Carbon Sequestration | 136 |
| 4.4 Effects of Methane Hydrates on Climate Change | 137 |
| 4.5 World's Methane Hydrate Resources | 141 |
| 4.5.1 Gas Hydrates on the North Slope, Alaska | 145 |
| 4.5.2 Gas Hydrates in the Gulf of Mexico | 145 |
| 4.5.3 Gas Hydrates in Russia's West Siberian Basin | 146 |
| 4.5.4 Gas Hydrates in Canada | 146 |
| 4.5.5 Projects Related to Methane Hydrates in Japan, India, China, Malaysia, and Korea | 147 |
| 4.5.6 A Case Study: Methane Hydrates in the Black Sea | 148 |
| 4.6 Properties of Methane Hydrates | 150 |
| 4.7 Methane Hydrate Stability | 152 |
| 4.8 Facilities for Recovery of Methane from Methane Hydrate | 156 |
| 4.8.1 Disposal of Impurities from Methane | 157 |
| 4.8.2 Gas Hydrate Research and Development | 157 |
| 4.9 Properties of Seawater | 159 |
| 4.10 Summary | 163 |
| Chapter 5 Processes for Methane Production from Gas Hydrates | 170 |
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| 5.1 Introduction | 170 |
| 5.2 Depressurization Process | 172 |
| 5.3 Thermal Stimulation Process | 174 |
| 5.4 Chemical Inhibitor Injection Process | 175 |
| 5.5 Gas Hydrate Reservoirs | 178 |
| 5.5.1 Arctic Hydrates | 178 |
| 5.5.2 Marine Hydrates | 179 |
| 5.6 Seafloor Drilling of the Hydrate Zone for Exploration and Production of Methane | 180 |
| 5.7 Possible Transportation Routes | 183 |
| 5.8 Economic and Political Issues | 185 |
| 5.9 Summary | 186 |
| Index | 192 |