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Electrochemical Methods in Archaeometry, Conservation and Restoration

:	Antonio Doménech-Carbó, María Teresa Doménech-Carbó, Virginia Costa
:	Electrochemical Methods in Archaeometry, Conservation and Restoration
:	Springer-Verlag
:	9783540928683
:	1
:	CHF 87.60
:

:	Physikalische Chemie
:	English

:	166
:	Wasserzeichen/DRM
:	PC/MAC/eReader/Tablet
:	PDF

Electrochemist y plays an important role in preserving our cultural heritage. For the first time this has been documented in the present volume. Coverage includes both electrochemical processes such as corrosion and electroanalytical techniques allowing to analyse micro- and nanosamples from works of art or archaeological finds. While this volume is primarily aimed at electrochemists and analytical chemists, it also contains relevant information for conservators, restorers, and archaeologists.

	Monographs in Electrochemistry	3
	Preface	6
	Contents	8
	List of Acronyms	10
	Introduction	13
	Chapter 1 Application of Instrumental Methods in the Analysis of Historic, Artistic and Archaeological Objects	15
	1.1 Importance of Scientific Examination for Archaeometry, Conservation and Restoration	15
	1.2 Information Provided by the Analytical Research	17
	1.3 Requirements of Analytical Methodology Applied to Archaeometric and Conservation Research	22
	1.4 An Overview on Analytical Methods Applied in Archaeometry and Conservation of Cultural Goods	26
	1.5 Final Considerations	45
	Chapter 2 Identification of Species by Electrochemical Methods	47
	2.1 Introduction	47
	2.2 Conventional Voltammetry	47
	2.3 Voltammetry of Microparticles	54
	2.4 Identification of Species Involving Electrochemically Depositable Metals	58
	2.5 Identification of Metallic Species	62
	2.6 Identification of Species Using Reductive/Oxidative Dissolution Process	63
	2.7 Identification of Species Via Solid-State Transformations	65
	2.8 Analytical Strategies	69
	Chapter 3 Resolution of Multicomponent Systems and Speciation	79
	3.1 Introduction	79
	3.2 Analysis of Single Multicomponent Systems	80
	3.3 Criteria for Pattern Recognition	82
	3.4 Bi-Parametric Data Analysis	84
	3.5 Multivariate Methods	98
	3.6 Speciation	101
	Chapter 4 Quantitative Methods	109
	4.1 Quantitation	109
	4.2 Phase Composition	110
	4.3 Relative Quantitation	111
	4.4 Absolute Quantitation, Standard Addition Method	120
	4.5 H-Point Standard Addition Methods	124
	Chapter 5 Electrochemical Basis of Corrosion of Cultural Objects	136
	5.1 A Search for Equilibrium	136
	5.2 Degradation Under Particular Conditions	138
	5.3 Some Useful Corrosion	146
	Chapter 6 Electrochemistry in Treatment and Conservation of Metal Artifacts	148
	6.1 Electrochemical Treatment of Metal Artifacts	148
	6.2 Evaluation of Museum Environment	152
	Bibliography	154
	About the Editor	169
	About the Authors	170
	Index	172