: Janis Matisons, Bogdan Marciniec
: Bogdan Marciniec
: Hydrosilylation A Comprehensive Review on Recent Advances
: Springer-Verlag
: 9781402081729
: 1
: CHF 419.50
:
: Organische Chemie
: English
: 408
: Wasserzeichen/DRM
: PC/MAC/eReader/Tablet
: PDF

For fifty years, Hydrosilylation has been one of the most fundamental and elegant methods for the laboratory and industrial synthesis of organosilicon and silicon related compounds. Despite the intensive research and continued interest generated by organosilicon compounds, no comprehensive book incorporating its various aspects has been published this century.

The aim of this book is to comprehensively review the advances of hydrosilylation processes since 1990. The survey of the literature published over the last two decades enables the authors to discuss the most recent aspects of hydrosilylation advances (catalytic and synthetic) and to elucidate the reaction mechanism for the given catalyst used and the reaction utilization. New catalytic pathways under optimum conditions necessary for efficient synthesis of organosilicon compounds are presented. This monograph shows the extensive development in the application of hydrosilylation in organic and asymmetric syntheses and in polymer and material science.

Preface7
Biographical Note9
Abbreviations11
Contents14
Introduction18
Part I Hydrosilylation of Carbon - CarbonMultiple Bonds in Synthesis of MolecularOrganosilicon Compounds24
Hydrosilylation of Alkenes and Their Derivatives25
Hydrosilylation of Alkynes and Their Derivatives74
Hydrosilylation of Carbon----Carbon Multiple Bonds in Organic Synthesis108
Asymmetric Hydrosilylation of Prochiral Alkenes and Their Derivatives145
Part II Hydrosilylation of Carbon - Carbon Multiple Bonds in Polymer Chemistry andMaterials Science177
Functionalisation and Cross-Linking of Organosilicon Polymers178
Hydrosilylation Polymerisation209
Functionalised (Poly)silsesquioxanes and Silicon- Containing Dendrimers233
Organosilicon – Organic Hybrid Polymers and Materials259
Part III Chemo- and Enantio-Selective Hydrosilylation of Unsaturated Carbon–Heteroatom Bonds305
Hydrosilylation of Unsaturated Carbon---- Heteroatom Bonds306
Asymmetric Hydrosilylation of Unsaturated Carbon– Heteroatom Bonds357
Index415