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Modern Aspects of Electrochemistry 42

:	Constantinos G. Vayenas, Ralph E. White, Maria E. Gamboa-Aldeco
:	Costas G Vayenas, Ralph E. White, Maria E. Gamboa-Aldeco
:	Modern Aspects of Electrochemistry 42
:	Springer-Verlag
:	9780387494890
:	1
:	CHF 97.20
:

:	Physikalische Chemie
:	English

:	424
:	Wasserzeichen/DRM
:	PC/MAC/eReader/Tablet
:	PDF

This volume analyzes and summarizes recent developments in several key interfacial electrochemical systems in the areas of fuel cell electrocatatalysis, electrosynthesis and electrodeposition. The six Chapters are written by internationally recognized experts in these areas and address both fundamental and practical aspects of several existing or emerging key electrochemical technologies. The Chapter by R. Adzic, N. Marinkovic and M. Vukmirovic provides a lucid and authoritative treatment of the electrochemistry and electrocatalysis of Ruthenium, a key element for the devel- ment of efficient electrodes for polymer electrolyte (PEM) fuel cells. Starting from fundamental surface science studies and interfacial considerations, this up-to-date review by some of the pioneers in this field, provides a deep insight in the complex catalytic-electrocatalytic phenomena occurring at the interfaces of PEM fuel cell electrodes and a comprehensive treatment of recent developments in this extremely important field. Several recent breakthroughs in the design of solid oxide fuel cell (SOFC) anodes and cathodes are described in the Chapter of H. Uchida and M. Watanabe. The authors, who have pioneered several of these developments, provide a lucid presentation d- cribing how careful fundamental investigations of interfacial electrocatalytic anode and cathode phenomena lead to novel electrode compositions and microstructures and to significant practical advances of SOFC anode and cathode stability and enhanced electrocatalysis.

	Preface	6
	Contents	8
	List of Contributors, MAE 42	16
	Some Recent Studies in Ruthenium Electrochemistry and Electrocatalysis	18
	I. INTRODUCTION	18
	II. PREPARATION OF WELL-ORDERED Ru SINGLE-CRYSTAL SURFACES	20
	III. ELECTROCHEMISTRY OF SINGLE-CRYSTAL Ru SURFACES	20
	IV. ELECTROCATALYSIS ON Ru SINGLE-CRYSTALS AND NANOPARTICLE SURFACES	37
	V. Pt-Ru FUEL CELL ELECTROCATALYSTS	49
	VI. CONCLUSIONS	64
	REFERENCES	65
	High-Performance Electrodes for Medium-Temperature Solid Oxide Fuel Cells	70
	I. INTRODUCTION	70
	II. ACTIVATION OF MIXED-CONDUCTING CERIA-BASED ANODE	75
	III. ACTIVATION OF MIXED-CONDUCTING PEROVSKITE-TYPE OXIDE CATHODES	84
	IV. EFFECTS OF IONIC CONDUCTIVITY OF ZIRCONIA ELECTROLYTES ON THE POLARIZATION PROPERTIES OF VARIOUS ELECTRODES IN SOFCS	94
	V. CONCLUSION	101
	REFERENCES	102
	Electrochemical CO2 Reduction on Metal Electrodes	105
	I. INTRODUCTION	105
	II. FUNDAMENTAL PROBLEMS	106
	III. OVERVIEWS OF ELECTROCHEMICAL REDUCTION OF CO2 AT METAL ELECTRODES	117
	IV. ELECTROACTIVE SPECIES IN THE ELECTROCHEMICAL REDUCTION OF CO2	133
	V. DEACTIVATION OF ELECTROCATALYTIC ACTIVITY OF METAL ELECTRODES	137
	VI. CLASSIFICATION OF ELECTRODE METALS AND REACTION SCHEME	143
	VII. ELECTROCHEMICAL REDUCTION OF CO2 TO CO AT SELECTED METAL AND NONMETAL ELECTRODES	157
	VIII. MECHANISTIC STUDIES OF ELECTROCHEMICAL REDUCTION OF CO2 AT Cu ELECTRODE	169
	IX. ATTEMPTS TO ENHANCE THE TRANSPORT PROCESS IN CO2 REDUCTION	191
	ACKNOWLEDGMENT	197
	LIST OF ABBREVIATIONS	197
	REFERENCES	198
	Induced Codeposition of Alloys of Tungsten, Molybdenum and Rhenium with Transition Metals	206
	I. INTRODUCTION	206
	II. CASE STUDIES	244
	III. CONCLUDING REMARKS	297
	ACKNOWLEDGEMENT	302
	APPENDICES	305
	25 Years of the Scanning Tunneling Microscopy	317
	I. INTRODUCTION	317
	II. STM LANDMARKS	320
	III. SUMMARY	371
	ACKNOWLEDGMENTS	374
	REFERENCES	374
	Modern Applications of Electrochemical Technology	383
	I. INTRODUCTION	383
	II. LIGA, AN IMPORTANT PROCESS IN MICRO-SYSTEM TECHNOLOGY	384
	III. APPLICATIONS IN SEMICONDUCTOR TECHNOLOGY	392
	IV. INFORMATION STORAGE: APPLICATIONS IN THE FIELDS OF MAGNETISM AND MICROELECTRONIC	406
	V. APPLICATIONS IN MEDICINE AND MEDICAL DEVICES	415
	VI. CONCLUSION	426
	REFERENCES	427
	Index	431