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N4-Macrocyclic Metal Complexes

:	José H. Zagal, Fethi Bedioui, Jean-Pol Dodelet
:	J.H. Zagal, Fethi Bedioui, J.P. Dodelet
:	N4-Macrocyclic Metal Complexes
:	Springer-Verlag
:	9780387284309
:	1
:	CHF 165.30
:

:	Physikalische Chemie
:	English

:	814
:	Wasserzeichen/DRM
:	PC/MAC/eReader/Tablet
:	PDF

In response to significant developments in sensor science and technology, this book offers insight into the various extended applications and developments of N4 macrocycle complexes in biomimetic electrocatalysis. Chapters are devoted to the chemistry, electronic and electrochemical properties of porphyrin- based polymetallated supramolecular redox catalysts and their applications in analytical and photoelectrochemical molecular devices; the use of porphyrins, phthalocyanines and related complexes as electrocatalysts for the detection of a wide variety of environmentally polluting and biologically relevant molecules; and the use of electropolymerized metalloporphyrin and metallophthalocyanine films as powerful materials for analytical tools, especially for sensing biologically relevant species.

	Contents	5
	Preface	15
	Contributors	17
	Billion-Year-Old Oxygen Cathode that Actually Works: Respiratory Oxygen Reduction and its Biomimetic Analogs	19
	1. The Basic Concepts of Energy Metabolism	19
	2. Biological Catalysis of Respiratory Oxygen Reduction	23
	3. Biomimetic Catalysis of O2 Reduction	30
	4. Summary and Conclusions: Lessons of Biomimetic O2 Reduction for the Design of Fuel Cell Catalysts	50
	Acknowledgments	53
	References	54
	Fundamental Aspects on the Catalytic Activity of Metallomacrocyclics for the Electrochemical Reduction of O2	59
	1. Introduction	59
	2. Reaction Pathways for the Reduction of Molecular Oxygen	60
	3. Interaction of O2 with Active Sites and the Redox Mechanism	64
	4. Two-Electron Reduction Catalysts for the Reduction of Molecular Oxygen	75
	5. Four-Electron Reduction Catalysts	78
	6. Conclusions	91
	Ackowledgments	93
	References	93
	Oxygen Reduction in PEM Fuel Cell Conditions: Heat- Treated Non- Precious Metal- N4 Macrocycles and Beyond	101
	1. Why Search for a Non-Pt Based Catalyst for the Reduction of O2 in PEM Fuel Cells?	101
	2. Activity of Electrocatalysts based on Fe - N4 and Co - N4 Macrocycles and Beyond	106
	3. Kinetic and Mechanistic Aspects of Electrochemical Oxygen Reduction	139
	4. Important Factors for the Use of Non-Noble Metal Electrocatalysts in PEM Fuel Cells for Automotive Applications	148
	5. Conclusions	155
	Acknowledgments	157
	References	157
	Biomimetic NOx Reductions by Heme Models and Proteins	166
	1. Introduction	166
	2. Native Enzymes for NOx Reductions	168
	3. Electrochemical Investigations of NOX Reduction	176
	4. Conclusions	197
	Acknowledgments	198
	References	198
	Electroreduction of CO2 Catalyzed By Metallomacrocycles	208
	1. Introduction	208
	2. Electroreduction of CO2 on Metallic Cathodes	210
	3. Biphenantroline and Bypiridine Hexaazacyclophane Systems	212
	4. Cyclam and Derivative Systems	221
	5. Phthalocyanines and Porphyrins Complexes	237
	6. Conclusions	260
	Acknowledgments	261
	References	261
	Supramolecular Porphyrins as Electrocatalysts	272
	1. Build-up of Supramolecular Porphyrins Based on Metal- Ligand Coordination	272
	2. Synthesis and Characterization of Tetrametallated Pyridyl Porphyrins	282
	3. Catalytic and Electrocatalytic Properties	295
	4. Electrochemical and Photoelectrochemical Properties of Porphyrin Films	304
	5. Final Remarks	318
	References	319